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Metamorphic Aureole in the Henry Mountains
A metamorphic aureole in the Henry Mountains, Utah. The greyish rock on top is the igneous intrusion, consisting of porphyritic granodiorite from the Henry Mountains laccolith, and the pinkish rock on the bottom is the sedimentary country rock, a siltstone. In between, the metamorphosed siltstone is visible as both the dark layer (~5cm thick) and the pale layer below it.

Metamorphism, in geology, is the change of the structure, texture, or composition of rocks. (an aggregation of solid matter composed of one or more of the minerals forming the earth's crust).

The scientific study of rocks is called petrology.

Rocks are commonly divided, according to their origin, into three major classes—Igneous, sedimentary, and metamorphic. They are caused by the effects of heat, deforming pressure, shearing stress, hot/chemically active fluids, or a combination of these. All of these changes occur while the rock remains essentially in the solid state. In theory, rocks are formed when the things surrounding them are in equilibrium with ambient physical conditions. If the conditions are changed by movements in the earth's crust or by igneous activity, metamorphism occurs to reestablish equilibrium and changes the physical character of the rock mass.

Metamorphic processes

Metamorphic Pressure alignment-white
(Left) Randomly-orientated grains in a rock before metamorphism. (Right) Grains align orthogonal to the applied stress if a rock is subjected to stress during metamorphism

Metamorphism is the set of processes by which existing rock is transformed physically or chemically at elevated temperature, without actually melting to any great degree. The importance of heating in the formation of metamorphic rock was first recognized by the pioneering Scottish naturalist, James Hutton, who is often described as the father of modern geology. Hutton wrote in 1795 that some rock beds of the Scottish Highlands had originally been sedimentary rock, but had been transformed by great heat.

Hutton also speculated that pressure was important in metamorphism. This hypothesis was tested by his friend, James Hall, who sealed chalk into a makeshift pressure vessel constructed from a cannon barrel and heated it in an iron foundry furnace. Hall found that this produced a material strongly resembling marble, rather than the usual quicklime produced by heating of chalk in the open air. French geologists subsequently added metasomatism, the circulation of fluids through buried rock, to the list of processes that help bring about metamorphism. However, metamorphism can take place without metasomatism (isochemical metamorphism) or at depths of just a few hundred meters where pressures are relatively low (for example, in contact metamorphism).

Rock can be transformed without melting because heat causes atomic bonds to break, freeing the atoms to move and form new bonds with other atoms. Pore fluid present between mineral grains is an important medium through which atoms are exchanged. This permits recrystallization of existing minerals or crystallization of new minerals with different crystalline structures or chemical compositions (neocrystallization). The transformation converts the minerals in the protolith into forms that are more stable (closer to chemical equilibrium) under the conditions of pressure and temperature at which metamorphism takes place.

Metamorphism is generally regarded to begin at temperatures of 100 to 200 °C (212 to 392 °F). This excludes diagenetic changes due to compaction and lithification, which result in the formation of sedimentary rocks. The upper boundary of metamorphic conditions lies at the solidus of the rock, which is the temperature at which the rock begins to melt. At this point, the process becomes an igneous process. The solidus temperature depends on the composition of the rock, the pressure, and whether the rock is saturated with water. Typical solidus temperatures range from 650 °C (1,202 °F) for wet granite at a few hundred megapascals (MPa) of pressure to about 1,080 °C (1,980 °F) for wet basalt at atmospheric pressure. Migmatites are rocks formed at this upper limit, which contains pods and veins of material that has started to melt but has not fully segregated from the refractory residue.

The metamorphic process can occur at almost any pressure, from near surface pressure (for contact metamorphism) to pressures in excess of 16 kbar (1600 MPa).

Types

Regional

Regional metamorphism is a general term for metamorphism that affects entire regions of the Earth's crust. It most often refers to dynamothermal metamorphism, which takes place in orogenic belts (regions where mountain building is taking place), but also includes burial metamorphism, which results simply from rock being buried to great depths below the Earth's surface in a subsiding basin.

Dynamothermal

The stones of the Dutch - Lleida Pyrenees 04
A metamorphic rock, deformed during the Variscan orogeny, at Vall de Cardós, Lérida, Spain

To many geologists, regional metamorphism is practically synonymous with dynamothermal metamorphism. This form of metamorphism takes place at convergent plate boundaries, where two continental plates or a continental plate and an island arc collide. The collision zone becomes a belt of mountain formation called an orogeny. The orogenic belt is characterized by thickening of the Earth's crust, during which the deeply buried crustal rock is subjected to high temperatures and pressures and is intensely deformed. Subsequent erosion of the mountains exposes the roots of the orogenic belt as extensive outcrops of metamorphic rock, characteristic of mountain chains.

Metamorphic rock formed in these settings tends to shown well-developed foliation. Foliation develops when a rock is being shortened along one axis during metamorphism. This causes crystals of platy minerals, such as mica and chlorite, to become rotated such that their short axes are parallel to the direction of shortening. This results in a banded, or foliated, rock, with the bands showing the colors of the minerals that formed them. Foliated rock often develops planes of cleavage. Slate is an example of a foliated metamorphic rock, originating from shale, and it typically shows well-developed cleavage that allows slate to be split into thin plates.

The type of foliation that develops depends on the metamorphic grade. For instance, starting with a mudstone, the following sequence develops with increasing temperature: The mudstone is first converted to slate, which is a very fine-grained, foliated metamorphic rock, characteristic of very low grade metamorphism. Slate in turn is converted to phyllite, which is fine-grained and found in areas of low grade metamorphism. Schist is medium to coarse-grained and found in areas of medium grade metamorphism. High-grade metamorphism transforms the rock to gneiss, which is coarse to very coarse-grained.

Rocks that were subjected to uniform pressure from all sides, or those that lack minerals with distinctive growth habits, will not be foliated. Marble lacks platy minerals and is generally not foliated, which allows its use as a material for sculpture and architecture.

Collisional orogenies are preceded by subduction of oceanic crust. The conditions within the subducting slab as it plunges toward the mantle in a subduction zone produce their own distinctive regional metamorphic effects, characterized by paired metamorphic belts.

The pioneering work of George Barrow on regional metamorphism in the Scottish Highlands showed that some regional metamorphism produces well-defined, mappable zones of increasing metamorphic grade. This Barrovian metamorphism is the most recognized metamorphic series in the world. However, Barrovian metamorphism is specific to pelitic rock, formed from mudstone or siltstone, and it is not unique even in pelitic rock. A different sequence in the northeast of Scotland defines Buchan metamorphism, which took place at lower pressure than the Barrovian.

Burial

Sioux Quartzite (Paleoproterozoic, 1.65 to 1.70 Ga; Transcontinental Arch, USA) 4
Sioux Quartzite, a product of burial metamorphism

Burial metamorphism takes place simply through rock being buried to great depths below the Earth's surface in a subsiding basin. Here the rock is subjected to high temperatures and the great pressure caused by the immense weight of the rock layers above. Burial metamorphism tends to produce low-grade metamorphic rock. This shows none of the effects of deformation and folding so characteristic of dynamothermal metamorphism.

Examples of metamorphic rocks formed by burial metamorphism include some of the rocks of the Midcontinent Rift System of North America, such as the Sioux Quartzite, and in the Hamersley Basin of Australia.

Contact

Metamorphic Aureole in the Henry Mountains
A metamorphic aureole in the Henry Mountains, Utah. The greyish rock on top is the igneous intrusion, consisting of porphyritic granodiorite from the Henry Mountains laccolith, and the pinkish rock on the bottom is the sedimentary country rock, a siltstone. In between, the metamorphosed siltstone is visible as both the dark layer (~5  cm thick) and the pale layer below it.
Rock contact metamorphism eng big text

Contact metamorphism occurs typically around intrusive igneous rocks as a result of the temperature increase caused by the intrusion of magma into cooler country rock. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole, the contact aureole, or simply the aureole. Contact metamorphic rocks are usually known as hornfels. Rocks formed by contact metamorphism may not present signs of strong deformation and are often fine-grained and extremely tough. The Yule Marble used on the Lincoln Memorial exterior and the Tomb of the Unknown Soldier in Arlington National Cemetery was formed by contact metamorphism.

Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact. The size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes generally have small aureoles with minimal metamorphism, extending not more than one or two dike thicknesses into the surrounding rock, whereas the aureoles around batholiths can be up to several kilometers wide.

The metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole. This is usually related to the metamorphic temperatures of pelitic or aluminosilicate rocks and the minerals they form. The metamorphic grades of aureoles at shallow depth are albite-epidote hornfels, hornblende hornfels, pyroxene hornfels, and sillimanite hornfels, in increasing order of temperature of formation. However, the albite-epidote hornfels is often not formed, even though it is the lowest temperature grade.

Magmatic fluids coming from the intrusive rock may also take part in the metamorphic reactions. An extensive addition of magmatic fluids can significantly modify the chemistry of the affected rocks. In this case the metamorphism grades into metasomatism. If the intruded rock is rich in carbonate the result is a skarn. Fluorine-rich magmatic waters which leave a cooling granite may often form greisens within and adjacent to the contact of the granite. Metasomatic altered aureoles can localize the deposition of metallic ore minerals and thus are of economic interest.

Fenitization, or Na-metasomatism, is a distinctive form of contact metamorphism accompanied by metasomatism. It takes place around intrusions of a rare type of magma called a carbonatite that is highly enriched in carbonates and low in silica. Cooling bodies of carbonatite magma give off highly alkaline fluids rich in sodium as they solidify, and the hot, reactive fluid replaces much of the mineral content in the aureole with sodium-rich minerals.

A special type of contact metamorphism, associated with fossil fuel fires, is known as pyrometamorphism.

Hydrothermal

Hydrothermal metamorphism is the result of the interaction of a rock with a high-temperature fluid of variable composition. The difference in composition between an existing rock and the invading fluid triggers a set of metamorphic and metasomatic reactions. The hydrothermal fluid may be magmatic (originate in an intruding magma), circulating groundwater, or ocean water. Convective circulation of hydrothermal fluids in the ocean floor basalts produces extensive hydrothermal metamorphism adjacent to spreading centers and other submarine volcanic areas. The fluids eventually escape through vents on the ocean floor known as black smokers. The patterns of this hydrothermal alteration are used as a guide in the search for deposits of valuable metal ores.

Shock

Shock metamorphism occurs when an extraterrestrial object (a meteorite for instance) collides with the Earth's surface. Impact metamorphism is, therefore, characterized by ultrahigh pressure conditions and low temperature. The resulting minerals (such as SiO2 polymorphs coesite and stishovite) and textures are characteristic of these conditions.

Dynamic

Dynamic metamorphism is associated with zones of high strain such as fault zones. In these environments, mechanical deformation is more important than chemical reactions in transforming the rock. The minerals present in the rock often do not reflect conditions of chemical equilibrium, and the textures produced by dynamic metamorphism are more significant than the mineral makeup.

There are three deformation mechanisms by which rock is mechanically deformed. These are cataclasis, the deformation of rock via the fracture and rotation of mineral grains; plastic deformation of individual mineral crystals; and movement of individual atoms by diffusive processes. The textures of dynamic metamorphic zones are dependent on the depth at which they were formed, as the temperature and confining pressure determine the deformation mechanisms which predominate.

At the shallowest depths, a fault zone will be filled with various kinds of unconsolidated cataclastic rock, such as fault gouge or fault breccia. At greater depths, these are replaced by consolidated cataclastic rock, such as crush breccia, in which the larger rock fragments are cemented together by calcite or quartz. At depths greater than about 5 kilometers (3.1 mi), cataclasites appear; these are quite hard rocks consist of crushed rock fragments in a flinty matrix, which forms only at elevated temperature. At still greater depths, where temperatures exceed 300 °C (572 °F), plastic deformation takes over, and the fault zone is composed of mylonite. Mylonite is distinguished by its strong foliation, which is absent in most cataclastic rock. It is distinguished from the surrounding rock by its finer grain size.

There is considerable evidence that cataclasites form as much through plastic deformation and recrystallization as brittle fracture of grains, and that the rock may never fully lose cohesion during the process. Different minerals become ductile at different temperatures, with quartz being among the first to become ductile, and sheared rock composed of different minerals may simultaneously show both plastic deformation and brittle fracture.

The strain rate also affects the way in which rocks deform. Ductile deformation is more likely at low strain rates (less than 10−14 sec−1) in the middle and lower crust, but high strain rates can cause brittle deformation. At the highest strain rates, the rock may be so strongly heated that it briefly melts, forming a glassy rock called pseudotachylite. Pseudotachylites seem to be restricted to dry rock, such as granulite.

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