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Amethyst
Amethyst. Magaliesburg, South Africa.jpg
Amethyst cluster from Magaliesburg, South Africa.
General
Category Silicate mineral
Formula
(repeating unit)
Silica (silicon dioxide, SiO2)
Crystal symmetry P3221 (no. 154)
Identification
Color Purple, violet, dark purple
Crystal habit 6-sided prism ending in 6-sided pyramid (typical)
Crystal system Trigonal
Twinning Dauphine law, Brazil law, and Japan law
Cleavage None
Fracture Conchoidal
Mohs scale hardness 7–lower in impure varieties
Luster Vitreous/glassy
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.65 constant; variable in impure varieties
Optical properties Uniaxial (+)
Refractive index nω = 1.543–1.553
nε = 1.552–1.554
Birefringence +0.009 (B-G interval)
Pleochroism Weak to moderate purple/reddish purple
Melting point 1650±75 °C
Solubility Insoluble in common solvents
Other characteristics Piezoelectric
Quartz gisements
Main amethyst-producing countries

Amethyst is a violet variety of quartz. The name comes from the Koine Greek αμέθυστος amethystos from α- a-, "not" and μεθύσκω (Ancient Greek) methysko / μεθώ metho (Modern Greek), "intoxicate", a reference to the belief that the stone protected its owner from drunkenness. Ancient Greeks wore amethyst and carved drinking vessels from it.

Amethyst, a semiprecious stone, is often used in jewelry and is the traditional birthstone for February.

Structure

Facet Cut Amethyst
Faceted amethyst
Amethyst close cropped
Emerald cut amethyst
Améthystre sceptre2
Amethyst crystals from Mexico

Amethyst is a purple variety of quartz (SiO2) and owes its violet color to irradiation, impurities of iron and in some cases other transition metals, and the presence of other trace elements, which result in complex crystal lattice substitutions. The hardness of the mineral is the same as quartz, thus making it suitable for use in jewelry.

Hue and tone

Amethyst occurs in primary hues from a light lavender or pale violet, to a deep purple. Amethyst may exhibit one or both secondary hues, red and blue. High quality amethyst can be found in Siberia, Sri Lanka, Brazil, Uruguay, and the Far East. The ideal grade is called "Deep Siberian" and has a primary purple hue of around 75–80%, with 15–20% blue and (depending on the light source) red secondary hues. ‘Rose de France’ is defined by its markedly light shade of the purple, reminiscent of a lavender/lilac shade. These pale colors were once considered undesirable, but have recently become popular due to intensive marketing.

Green quartz is sometimes incorrectly called green amethyst, which is a misnomer and not an appropriate name for the material, as the proper terminology is prasiolite. Other names for green quartz are vermarine or lime citrine.

Amethyst frequently shows color zoning, with the most intense color typically found at the crystal terminations. It is the most prized variety of quartz. One of a gem cutter’s tasks is to make a finished product with even color. Sometimes, only a thin layer of a natural, uncut amethyst is violet colored, or the color is very uneven. The uncut gem may have only a small portion that is suitable for faceting.

The color of amethyst has been demonstrated to result from substitution by irradiation of trivalent iron (Fe3+) for silicon in the structure, in the presence of trace elements of large ionic radius, and to a certain extent, the amethyst color can naturally result from displacement of transition elements even if the iron concentration is low. Natural amethyst is dichroic in reddish violet and bluish violet, but when heated, turns yellow-orange, yellow-brown, or dark brownish and may resemble citrine, but loses its dichroism, unlike genuine citrine. When partially heated, amethyst can result in ametrine.

Amethyst can fade in tone if overexposed to light sources and can be artificially darkened with adequate irradiation. It does not fluoresce under either short-wave or long-wave UV light.

Geographic distribution

Amethyst is found in many locations around the world. Between 2000 and 2010, the greatest production was from Marabá and Pau d'Arco, Pará, and the Paraná Basin, Rio Grande do Sul, Brazil; Sandoval, Santa Cruz, Bolivia; Artigas, Uruguay; Kalomo, Zambia; and Thunder Bay, Ontario. Lesser amounts are found in many other locations in Africa, Brazil, Spain, Argentina, Russia, Afghanistan, South Korea, Mexico, and the United States.

Druse
An amethyst geode that formed when large crystals grew in open spaces inside the rock.

Amethyst is produced in abundance in the state of Rio Grande do Sul in Brazil where it occurs in large geodes within volcanic rocks. Many of the hollow agates of southwestern Brazil and Uruguay contain a crop of amethyst crystals in the interior. Artigas, Uruguay and neighboring Brazilian state Rio Grande do Sul are large world producers, with lesser quantities mined in Minas Gerais and Bahia states.

Minirals museum IMG 20180620 151046
Amethyst from Brazil in the Mineral museum in India

Amethyst is also found and mined in South Korea. The large opencast amethyst vein at Maissau, Lower Austria, was historically important, but is no longer included among significant producers. Much fine amethyst comes from Russia, especially near Mursinka in the Ekaterinburg district, where it occurs in drusy cavities in granitic rocks. Amethyst was historically mined in many localities in south India, though these are no longer significant producers. One of the largest global amethyst producers is Zambia in southern Africa with an annual production of about 1000 tons.

Amethyst occurs at many localities in the United States. The most important production is at Four Peaks, Gila and Maricopa Counties, Arizona, and Jackson's Crossroads, Wilkes County, Georgia.

Smaller occurrences have been reported in the Red Feather Lakes, near Fort Collins, Colorado; Amethyst Mountain, Texas; Yellowstone National Park; Delaware County, Pennsylvania; Haywood County, North Carolina; Deer Hill and Stow, Maine and in the Lake Superior region of Minnesota, Wisconsin , and Michigan.

Amethyst is relatively common in the Canadian provinces of Ontario and Nova Scotia. The largest amethyst mine in North America is located in Thunder Bay, Ontario.

Amethyst is the official state gemstone of South Carolina. Several South Carolina amethysts are on display at the Smithsonian Museum of Natural History.

History

Intaglio Caracalla Cdm Paris Chab2101
Roman intaglio engraved gem of Caracalla in amethyst, once in the Treasury of Sainte-Chapelle.
Uninscribed amethyst scarab at the center of a string of amethyst ball beads. Middle Kingdom. From Egypt. The Petrie Museum of Egyptian Archaeology, London
Uninscribed amethyst scarab at the center of a string of amethyst ball beads. Middle Kingdom. From Egypt. The Petrie Museum of Egyptian Archaeology, London

Amethyst was used as a gemstone by the ancient Egyptians and was largely employed in antiquity for intaglio engraved gems.

Medieval European soldiers wore amethyst amulets as protection in battle in the belief that amethysts heal people and keep them cool-headed. Beads of amethyst were found in Anglo-Saxon graves in England. Anglican bishops wear an episcopal ring often set with an amethyst.

A large geode, or "amethyst-grotto", from near Santa Cruz in southern Brazil was presented at a 1902 exhibition in Düsseldorf, Germany.

The meaning of amethyst varies from time to time and culture, which is why amethyst has different meanings in Feng Shui and focuses on increasing wealth. In ancient China, it was also used as a powerful tool to remove negative energies and drive away the hazards of daily life.

Synthetic amethyst

Synthetic (laboratory-grown) amethyst is produced by a synthesis method called hydrothermal growth, which grows the crystals inside a high-pressure autoclave.

Synthetic amethyst is made to imitate the best quality amethyst. Its chemical and physical properties are the same as that of natural amethyst and it can not be differentiated with absolute certainty without advanced gemmological testing (which is often cost-prohibitive). One test based on "Brazil law twinning" (a form of quartz twinning where right and left hand quartz structures are combined in a single crystal) can be used to identify most synthetic amethyst rather easily. Synthesizing twinned amethyst is possible, but this type is not available in large quantities in the market.

Treated amethyst is produced by gamma ray, X-ray, or electron-beam irradiation of clear quartz (rock crystal), which has been first doped with ferric impurities. Exposure to heat partially cancels the irradiation effects and amethyst generally becomes yellow or even green. Much of the citrine, cairngorm, or yellow quartz of jewelry is said to be merely "burnt amethyst".

Cultural history

Tibetans consider amethyst sacred to the Buddha and make prayer beads from it. Amethyst is considered the birthstone of February. In the Middle Ages, it was considered a symbol of royalty and used to decorate English regalia. In the Old World, amethyst was considered one of the Cardinal gems, in that it was one of the five gemstones considered precious above all others, until large deposits were found in Brazil.

Value

Until the 18th century, amethyst was included in the cardinal, or most valuable, gemstones (along with diamond, sapphire, ruby, and emerald), but since the discovery of extensive deposits in locations such as Brazil, it has lost most of its value. It is now considered a semiprecious stone.

Collectors look for depth of color; possibly with red flashes if cut conventionally. As amethyst is readily available in large structures, the value of the gem is not primarily defined by carat weight. This is different from most gemstones, since the carat weight typically exponentially increases the value of the stone. The biggest factor in the value of amethyst is the color displayed.

The highest-grade amethyst (called "Deep Russian") is exceptionally rare. When one is found, its value is dependent on the demand of collectors. The highest-grade sapphires or rubies are still orders of magnitude more expensive than amethyst.

Handling and care

The most suitable setting for gem amethyst is a prong or a bezel setting. The channel method must be used with caution.

Amethyst has a good hardness, and handling it with proper care will prevent any damage to the stone. Amethyst is sensitive to strong heat and may lose or change its colour when exposed to prolonged heat or light. Polishing the stone or cleaning it by ultrasonic or steamer must be done with caution.

See also

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